98418-97-4

Upstream product

• 122258-63-3 (E)-2,4,4-trimethyl-3-(3'-methyl-1',3'-butadienyl)-2-cyclohexen-1-ol 
• 98418-95-2 (E)-2,4,4-trimethyl-3-(3'-methyl-1',3'-butadienyl)-2-cyclohexenyl acetate 
• 74345-31-6 2,4,4-trimethyl-3-(3-oxobut-1-enyl)cyclohex-2-enyl acetate 

Downstream Products

• 1198339-66-0 trisporin A 
• 54483-82-8 trisporin B 
• 77399-83-8 2,4,4-trimethyl-3-((1E,3E)-3-methyl-7-oxo-octa-1,3-dienyl)cyclohex-2-enone 
• 1198339-75-1 C₂₄H₄₂O₂Si 
• 929626-45-9 C₂₄H₄₂O₂Si 
• 98418-98-5 (E)-1,2,4,4-tetramethyl-3-(3'-methyl-1',3'-butadienyl)-2-cyclohexen-1-ol 

Relevant academic research and scientific papers

A convenient cross-metathesis approach to trisporins

Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the key step. This reaction has proved to be highly regioselective, allowing the combination of α- or β-ionone derivatives having a 1,1-disustituted olefin with

73. Photochemistry of 5,6-Epoxy-1,3-dienes in the Ionone Series. Influence of a Hydroxy Group in the 7-Position

The synthesis and photolyses of the epoxydiene (E)-5 are described.On triplet excitation (λ>280 nm, acetone), (E)-5 undergoes initial cleavage of the C(5)-O bond leading to the intermediate c.Presumably an H-shift (c->e) followed by the fragmentation of t