IODOTRIMETHYLSILANE DEOXYGENATION OF CARBONYL CONJUGATED ALLYLIC ETHERS

DOI: 10.1016/S0040-4039(01)80271-9

Source and publish data:

Tetrahedron Letters p. 645 - 646 (1989)

Update date:2022-08-24

Topics:

Authors:

Hartman, David A.

Curley, Robert W. Jr.

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Article abstract of DOI:10.1016/S0040-4039(01)80271-9

The attempted demethylation of 4-methoxy-β-ionone (1) with iodotrimethylsilane gave the unexpected product, β-ionone (2).This reagent may prove useful in the cleavage of allylic ethers conjugated to ketones.

Full text of DOI:10.1016/S0040-4039(01)80271-9

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