12257-35-1Relevant articles and documents
Direct Comparison of the reactivity of model complexes for compounds 0, I, and II in oxygenation, hydrogen-abstraction, and hydride-transfer processes
Fertinger, Christoph,Hessenaue-Ilicheva, Natalya,Franke, Alicja,Van Eldik, Rudi
supporting information; scheme or table, p. 13435 - 13440 (2010/06/11)
The iron(III) meso-tetramesitylporphyrin complex is a good biomimetic to study the catalytic reactions of cytochrome P450. All of the three most discussed reactive intermediates concerning P450 catalysis (namely, Cpd 0, Cpd I, and Cpd II) can be selective
Kinetic study of the hydrogen abstraction reaction of the benzotriazole-N-oxyl radical (BTNO) with H-donor substrates
Brandi, Paolo,Galli, Carlo,Gentili, Patrizia
, p. 9521 - 9528 (2007/10/03)
The aminoxyl radical (>N-O.) BTNO (benzotriazole-N-oxyl) has been generated by the oxidation of 1-hydroxybenzotriazole (HBT; >N-OH) with a CeIV salt in MeCN. BTNO presents a broad absorption band with λmax 474 nm and e 184
Kinetics of the reaction of the TEMPO radical with alkylarenes
Opeida,Matvienko,Bakurova,Voloshkin
, p. 900 - 904 (2007/10/03)
The kinetics of the reaction of the stable radical 2,2,6,6- tetramethylpiperidine-N-oxyl (TEMPO) with a series of alkylarenes containing primary and secondary benzyl C-H bonds was studied by ESR, and the reaction rate constants were determined. The scheme
