1227005-07-3Relevant academic research and scientific papers
Reactivity of the nickel(0)-CO2-imine system: New pathway to vicinal diamines
Graet, Alexandre,Sinault, Laura,Fusaro, Maxime B.,Vallet, Anne-Laure,Seu, Candace,Kilgore, James L.,Baum, Marc M.
, p. 1997 - 2000 (2010)
Nickela-2-oxazolidinones, formed by oxidative coupling of imines and CO2 with Ni0, react with LiCl under mild conditions (4 °C, 1 atm) to afford vicinal diamines in up to 89% yield. The reaction is the first organometallic example of
