329-24-8Relevant academic research and scientific papers
Kinetic and thermodynamic modulation of dynamic imine libraries driven by the hexameric resorcinarene capsule
Gambaro, Stefania,Talotta, Carmen,Della Sala, Paolo,Soriente, Annunziata,De Rosa, Margherita,Gaeta, Carmine,Neri, Placido
, p. 14914 - 14923 (2020/10/13)
The composition of dynamic covalent imine libraries (DCL) adapts to the presence of the hexameric resorcinarene capsule. In the presence of the self-assembled capsule, a kinetic and thermodynamic modulation of the imine constituents of the DCLs was observed, which was induced by an unusual predatory action of the capsule on specific imine constituents. More complex 2 × 2 DCLs also adapt to the presence of the hexameric capsule, showing a thermodynamic and kinetic modulation of the constituents induced by the predatory action of the capsule. By cross-referencing experimental data, a good selectivity (up to 66%) for one constituent can be induced in a 2 × 2 DCL.
(1-Alkynyl)dicarbonylcyclopentadienyliron complexes as electron-rich alkynes in organic synthesis: BF3-mediated [2+2] cycloaddition/ring- opening providing (2-alkenyl-1-imino)iron complexes
Nakaya, Ryotaro,Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
supporting information; experimental part, p. 8559 - 8561 (2011/09/20)
Strike while the iron is hot! A BF3-mediated formal [2+2] cycloaddition between (1-alkynyl)iron complexes and aromatic aldehyde imines occurs, which is followed by ring-opening of the initially formed azacyclobutenes to yield (2-alkenyl-1-imino)iron complexes (see scheme). The resulting iron complexes undergo deferric substitution reactions with water under oxidative conditions to afford the corresponding cinnamamides with high E selectivity.
β-Lactam derivatives as enzyme inhibitors: Halogenated β-lactams and related compounds
Elriati, Ali,Loose, Jutta,Mayrhofer, Roswitha,Bergmann, Hans-Joachim,Otto, Hans-Hartwig
experimental part, p. 835 - 846 (2009/09/06)
Different modifications of the imine - acyl chloride reaction were used for the synthesis of 3-mono- and 3,3-dihalogenated 1,4-diaryl substituted β-lactams. Furthermore, these β-lactams were modified by halogen substitution either at the aryl at position
SYNTHESE VON FLUORIERTEN N-ARYLAMINO-ARYLMETHANPHOSPHONSAEUREDIALKYLESTERN
Gruss, Ulrike,Haegele, Gerhard
, p. 209 - 222 (2007/10/02)
Fluorinated α-C- and N-arylsubstituted aminomethanephosphonic acid diethylesters 5 are prepared in high yields by a "two-step" procedure: mixing equimolar amounts of fluorinated benzaldehydes 1 and anilines 2 to benzaldehyde-(N-aryl-)imines 3.Subsequently
