122888-45-3Relevant academic research and scientific papers
Gold-catalyzed cycloisomerizations of ene-ynamides
Couty, Sylvain,Meyer, Christophe,Cossy, Janine
experimental part, p. 1809 - 1832 (2009/06/28)
The gold-catalyzed cycloisomerizations of 1,6-ene-ynamides proceed under mild conditions and lead to cyclobutanones from terminal or trimethylsilyl substituted ynamides, or to carbonyl compounds bearing a 2,3-methanopyrrolidine subunit from substrates pos
Configuration-dependent ring opening of silyloxiranes: synthesis of functionalized alkenes or tetrahydrofurans
Lange, Jens,Schaumann, Ernst
experimental part, p. 4674 - 4684 (2009/12/06)
cis- and trans-Silyloxiranes with a potential tosylate or bromide leaving group in the β position are available by the diastereospecific reduction of the corresponding alkynes with DIBAL-H and hydrosilylation with silanes, respectively. In the reaction wi
