122888-53-3

Upstream product

• 492440-09-2 4-(dimethyl(phenyl)silyl)but-3-yn-1-ol 
• 122888-45-3 dimethylphenyl[(Z)-4-(tetrahydropyran-2-yloxy)but-1-enyl]silane 
• 768-33-2 phenyldimethylsilyl chloride 
• 766-77-8 Dimethylphenylsilane 
• 927-74-2 3-Butyn-1-ol 
• 122888-52-2 dimethyl(phenyl)(4-((tetrahydro-2H-pyran-2-yl)oxy)but-1-yn-1-yl)-silane 

Downstream Products

• 1138502-28-9 2-[(Z)-4-(dimethylphenylsilyl)but-3-enyl]isoindole-1,3-dione 
• 87682-62-0 (Z)-4-(trimethylsilyl)but-3-enyl 4-methylbenzene sulfonate 
• 1224951-91-0 (Z)-4-(dimethyl(phenyl)silyl)but-3-enyl methanesulfonate 
• 104080-51-5 trans-1-(dimethylphenylsilyl)-1-buten-4-ol 
• 122888-57-7 (Z)-(4S,5RS)-acetyloxy-1-<4-(dimethylphenylsilyl)-3-butenyl>-5-phenylthio-2-pyrrolidinone 
• 122888-59-9 (E)-3S-1-acetyloxy-1-<4-(dimethylphenylsilyl)-3-butenyl>-2,5-pyrrolidinedione 
• 122888-55-5 (Z)-(4S,5RS)-4,5-diacetyloxy-1-<4-(dimethylphenylsilyl)-3-butenyl>-2-pyirrolidinone 
• 122888-54-4 (Z)-3S-acetyloxy-1-<4-(dimethylphenylsilyl)-3-butenyl>-2,5-pyrrolidinedione 

Relevant academic research and scientific papers

Regio- and enantioselective monoborylation of alkenylsilanes catalyzed by an electron-donating chiral phosphine-Copper(I) complex

An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding opticall

Stereospecific synthesis of cyclobutylboronates through copper(I)-catalyzed reaction of homoallylic sulfonates and a diboron derivative

A copper(I)-catalyzed stereospecific reaction for the preparation of cis- and trans-1-silyl-2-borylcyclobutanes as well as 1-phenyl-2-borylcyclobutanes is reported. (Z)- and (E)-Homoallylic methanesulfonates were converted to the corresponding trans- and

Gold-catalyzed cycloisomerizations of ene-ynamides

The gold-catalyzed cycloisomerizations of 1,6-ene-ynamides proceed under mild conditions and lead to cyclobutanones from terminal or trimethylsilyl substituted ynamides, or to carbonyl compounds bearing a 2,3-methanopyrrolidine subunit from substrates pos

Configuration-dependent ring opening of silyloxiranes: synthesis of functionalized alkenes or tetrahydrofurans

cis- and trans-Silyloxiranes with a potential tosylate or bromide leaving group in the β position are available by the diastereospecific reduction of the corresponding alkynes with DIBAL-H and hydrosilylation with silanes, respectively. In the reaction wi

Hydrosilylation of alkynes catalyzed by ruthenium carbene complexes

Hydrosilylation of terminal alkynes with a variety of silanes catalyzed by Cl2(PCy3)2RuCHPh (1) affords mainly the Z-isomer via trans addition in excellent yields. The presence of a hydroxyl group in close proximity to the