1229-49-8Relevant academic research and scientific papers
Visible-light-triggered direct benzoyloxylation of electron-rich arenes at room temperature without chelation assistance
Rao, Honghua,Wang, Ping,Li, Chao-Jun
supporting information, p. 6503 - 6507 (2013/01/15)
A RuII photocatalytic method was developed for the direct mono-benzoyloxylation of electron-rich aromatic and heteroaromatic systems even with an excess amount of benzoyl peroxide. The reaction was conducted at room temperature under visible light. The direct ArC-H benzoyloxylations occur without the assistance of any directing groups and can also tolerate various functional groups that have already shown diverse reactivities in transition-metal catalysis.
