123-18-2Relevant articles and documents
Direct Synthesis of Renewable Dodecanol and Dodecane with Methyl Isobutyl Ketone over Dual-Bed Catalyst Systems
Sheng, Xueru,Li, Ning,Li, Guangyi,Wang, Wentao,Wang, Aiqin,Cong, Yu,Wang, Xiaodong,Zhang, Tao
, p. 825 - 829 (2017/03/17)
For the first time, we demonstrated two integrated processes for the direct synthesis of dodecanol or 2,4,8-trimethylnonane (a jet fuel range C12-branched alkane) using methyl isobutyl ketone (MIBK) that can be derived from lignocellulose. The reactions were carried out in dual-bed continuous flow reactors. In the first bed, MIBK was selectively converted to a mixture of C12 alcohol and ketone. Over the Pd-modified magnesium– aluminium hydrotalcite (Pd-MgAl-HT) catalyst, a high total carbon yield (73.0 %) of C12 oxygenates can be achieved under mild conditions. In the second bed, the C12 oxygenates generated in the first bed were hydrogenated to dodecanol over a Ru/C catalyst or hydrodeoxygenated to 2,4,8-trimethylnonane over a Cu/SiO2 catalyst. The as-obtained dodecanol can be used as feedstock in the production of sodium dodecylsulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS), which are widely used as surfactants or detergents. The asobtained 2,4,8-trimethylnonane can be blended into conventional jet fuel without hydroisomerization.
Multifunctional catalysis by Pd@MIL-101: One-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal-organic framework
Pan, Yingyi,Yuan, Bizhen,Li, Yingwei,He, Dehua
supporting information; experimental part, p. 2280 - 2282 (2010/07/09)
Palladium nanoparticles deposited on a chromium terephthalate MIL-101 is a highly efficient multifunctional catalyst for the one-step synthesis of methyl isobutyl ketone, with significantly higher activity than palladium on traditional materials, such as metal oxides and zeolites.
Multifunctional catalysis by Pd-polyoxometalate: One-step conversion of acetone to methyl isobutyl ketone
Hetterley, Robert D.,Kozhevnikova, Elena F.,Kozhevnikov, Ivan V.
, p. 782 - 784 (2008/02/03)
Pd metal supported on Cs2.5H0.5PW12O 40 is an efficient bifunctional catalyst for the one-step conversion of acetone to methyl isobutyl ketone in gas and liquid phase. The Royal Society of Chemistry 2006.