123027-91-8

Upstream product

• 614-76-6 N-acetyl-2-bromoaniline 
• 109669-44-5 tributyl-[3-(tetrahydropyran-2-yloxy)-1-propynyl]stannane 
• 615-43-0 2-iodophenylamine 
• 75-36-5 acetyl chloride 
• 287477-27-4 2-[3-(tetrahydro-2H-pyran-2-yloxy)prop-1-yn-1-yl]aniline 
• 6089-04-9 3-(tetrahydropyran-2'-yloxy)propyne 

Downstream Products

• 1310368-13-8 N-[2-(1-methoxy-1H-indol-2-yl)prop-2-en-1-yl]-N-{2-[3-(tetrahydro-2H-pyran-2-yloxy)prop-1-yn-1-yl]phenyl}acetamide 
• 1310368-11-6 (4Z)-4-[1-(1-methoxy-1H-indol-2-yl)-2-(tetrahydro-2H-pyran-2-yloxy)ethylidene]-3-methylidene-1-(prop-1-en-2-yl)-1,2,3,4-tetrahydroquinoline 
• 1310368-12-7 N-(2-bromoprop-2-en-1-yl)-N-{2-[3-(tetrahydro-2H-pyran-2-yloxy)prop-1-yn-1-yl]phenyl}-acetamide 

Relevant academic research and scientific papers

Total synthesis of calothrixins A and B by palladium-catalyzed tandem cyclization/cross-coupling reaction of indolylborate

The palladium-catalyzed tandem cyclization/cross-coupling reaction of triethyl(indol-2-yl)borate with vinyl bromide was successfully used in the concise total synthesis of the indolophenanthridine alkaloids, calothrixins A and B. Palladium-catalyzed cross

Concise total synthesis of calothrixins A and B

The concise total synthesis of calothrixins A and B has been accomplished by utilizing the one-pot formation of hexatriene as a key intermediate via the palladium-catalyzed tandem cyclization/cross-coupling reaction of triethyl(indol-2-yl)borate. In anoth