123135-93-3

Upstream product

• 26981-77-1 t-butylallene 
• 79184-72-8 2,2-dimesitylhexamethyltrisilane 
• 17576-75-9 N,N-dimethyl-cyclohexylamine N-oxide 
• 110547-61-0 (Z)-1,1-dimesityl-2-neopentylidenesilirane 

Downstream Products

• 123135-94-4 (Z)-2-[Hydroxy-bis-(2,4,6-trimethyl-phenyl)-silanyl]-4,4-dimethyl-pent-2-en-1-ol 

Relevant academic research and scientific papers

NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES

1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr

REGIOSPECIFIC FORMATION OF ALKYLIDENE-1,2-OXASILETANE

A new type of 1,2-oxasiletane, alkylidene-1,2-oxasiletane was prepared by oxidation of alkylidenesilirane.Reaction of 1,1-dimesityl-2-Z-neopentylidenesilirane with cyclohexyldimethylamine N-oxide and diphenyl sulfoxide regiospecifically gave 2,2-dimesityl-3-Z-neopentylidene-1,2-oxasiletane (44 percent) and 4-Z-isomer (70 percent), respectively.Both oxasiletanes were thermally stable not to undergo a retro (2+2) reaction