123228-01-3Relevant academic research and scientific papers
A novel method for introducing a polyfluoroalkyl group into aromatic compounds
Tahara, Ryuhei,Fukuhara, Tadahito,Hara, Shoji
experimental part, p. 579 - 586 (2011/09/20)
Introduction of a polyfluoroalkyl group into aromatic compounds was achieved by Friedel-Crafts reaction using (1-chloro-1-hydroperfluoroalkyl) sulfides 1, and the subsequent desulfurizing-difluorination of the resulting product using IF5/Etsub
Generation and Electrophilic Reactions of the 2,2,2-Trifluoro-1-(phenylthio)ethyl Carbocation
Uneyama, Kenji,Momota, Makoto,Hayashida, Kazuaki,Itoh, Toshiyuki
, p. 5364 - 5368 (2007/10/02)
2,2,2-Trifluoro-1-(phenylthio)ethyl carbocation (4) has been generated by the reaction of 1-chloro-2,2,2-trifluoroethyl phenyl sulfide (7b) with ZnCl2 in nitromethane or SnCl4 in 1,2-dichloroethane.The carbocation 4 can be trapped with various aromatics b
GENERATION AND REACTION OF 2,2,2-TRIFLUORO-1-PHENYLSULFENYLETHYL CARBOCATION
Uneyama, Kenji,Momota, Makoto
, p. 2265 - 2266 (2007/10/02)
Lewis acid-catalyzed dechlorination of 1-chloro-2,2,2-trifluoroethyl phenyl sulfide generates 2,2,2-trifluoro-1-phenylsulfenylethyl carbocation which undergoes electrophilic reaction with aromatic compounds.
