123268-74-6Relevant academic research and scientific papers
Stereoretentive introduction of (E)- And (Z)-γ-alkoxyallyl groups into carbonyl compounds via light-promoted reaction with γ-alkoxyallylstannanes
Takuwa, Akio,Nishigaichi, Yutaka,Ebara, Seiji,Iwamoto, Hidetoshi
, p. 1789 - 1790 (1998)
The light-promoted condensation between carbonyl compounds and (E)- or (Z)-γ-alkoxyallylstannanes affords predominantly the linear homoallylic alcohols, with retention of the double bond geometry of the γ-alkoxyallyl moieties.
SILOXY-WITTIG REARRANGEMENT: A NEW METHOD FOR DIASTEREOSELECTIVE PREPARATIONS OF 1,2-DIOL SYSTEMS
Nakai, Ei-ichi,Nakai, Takeshi
, p. 5409 - 5412 (2007/10/02)
A novel Wittig variant, termed "siloxy-Wittig rearrangement", has been developed which provides the half-silylated 1,2-diol systems with a high anti-diastereoselectivity.The unusual anti-selectivity is discussed on mechanistic grounds.
