123312-24-3

Basic information

• Product Name: 1-methoxy-3-[1-(nitromethyl)propyl]benzene
• Synonyms: 1-methoxy-3-[1-(nitromethyl)propyl]benzene
• CAS NO: 123312-24-3
• Molecular Weight: 209.245
• Mol File: 123312-24-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-methoxy-3-[1-(nitromethyl)propyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-3-[1-(nitromethyl)propyl]benzene(123312-24-3)
• EPA Substance Registry System: 1-methoxy-3-[1-(nitromethyl)propyl]benzene(123312-24-3)

Safety Data

• Hazardous Substances Data: 123312-24-3(Hazardous Substances Data)

Upstream product

• 3179-09-7 (E)-1-methoxy-3-(2-nitrovinyl)benzene 
• 557-20-0 diethylzinc 
• 123312-23-2 2-(3-methoxyphenyl)-1-nitroethane 
• 75-03-6 ethyl iodide 
• 591-31-1 3-methoxy-benzaldehyde 
• 3179-09-7 1-methoxy-3-(2-nitrovinyl)benzene 

Downstream Products

• 123312-30-1 2-(2-Bromo-5-methoxy-phenyl)-N-[2-(3-methoxy-phenyl)-butyl]-acetamide 
• 123312-35-6 1-(2-Bromo-5-methoxy-benzyl)-4-ethyl-6-methoxy-1,2,3,4-tetrahydro-isoquinoline 
• 123312-25-4 2-(3-methoxyphenyl)-1-butanamine 

Relevant articles and documents

Application of the chiral bis(phosphine) monoxide ligand to catalytic enantioselective addition of dialkylzinc reagents to β-nitroalkenes

(Chemical Equation Presented) Me-DuPHOS monoxide is shown to be a very effective ligand in the enantioselective copper-catalyzed addition of dialkylzinc reagents to β-nitroalkenes providing access to chiral nitroalkanes. The major advantages of this process are high yields, broad and complementary substrate scope, and high enantioselectivities. The effect of achiral dummy ligands as an additive has also been documented.

C-C-Kupplung am vinylischen Kohlenstoffatom unter NO2-/Alkyl-Substitution bei der Umsetzung von 2-Aryl-1-nitro-1-alkenen mit Dialkylzinkverbindungen - eine neue Reaktion

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