123367-68-0Relevant academic research and scientific papers
Synthesis of the rarely obtained syn-Adducts in the Reaction of Organocopper Compounds with 2,3-O-Isopropylideneglyceraldehyde. Preparation of Optically Active Epoxy Alcohols
Sato, Fumie,Kobayashi, Yuichi,Takahashi, Osamu,Chiba, Tsunehisa,Takeda, Yoshiyuki,Kusakabe, Masato
, p. 1636 - 1638 (1985)
Organocopper compounds, prepared from Grignard reagents and copper(I) iodide in tetrahydrofuran-dimethyl sulphide, react with 2,3-O-isopropylideneglyceraldehyde highly stereoselectively (>10:1) affording the rarely obtained syn-addition products which can be readily converted into optically active epoxy alcohols, useful intermediates in organic synthesis.
GLYCALS IN STEREOSPECIFIC SYNTHESIS. I. SYNTHESIS OF (+)-cis-DISPARLURE - THE SEX PHEROMONE OF THE GYPSY MOTH (Porthetria dispar L.)
Tolstikov, A. G.,Khakhalina, N. V.,Odinokov, V. N.,Khalilov, L. M.,Spirikhin L. V.
, p. 263 - 268 (2007/10/02)
An original approach to the synthesis of 2R,3S-epoxy-1-hydroxytridecane was developed on the basis of tri-O-acetyl-D-galactal.The product was used as the key synthon in the production of a sample of (+)-cis-disparlure with high optical purity.
