Journal of the Chemical Society. Chemical communications p. 1636 - 1638 (1985)
Update date:2022-08-04
Topics:
Sato, Fumie
Kobayashi, Yuichi
Takahashi, Osamu
Chiba, Tsunehisa
Takeda, Yoshiyuki
Kusakabe, Masato
Organocopper compounds, prepared from Grignard reagents and copper(I) iodide in tetrahydrofuran-dimethyl sulphide, react with 2,3-O-isopropylideneglyceraldehyde highly stereoselectively (>10:1) affording the rarely obtained syn-addition products which can be readily converted into optically active epoxy alcohols, useful intermediates in organic synthesis.
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