123411-89-2

Basic information

• Product Name: ((1S,2R)-2-Hydroxy-1-isopropyl-pent-4-enyl)-carbamic acid benzyl ester
• Synonyms: ((1S,2R)-2-Hydroxy-1-isopropyl-pent-4-enyl)-carbamic acid benzyl ester
• CAS NO: 123411-89-2
• Molecular Weight: 277.364
• Mol File: 123411-89-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((1S,2R)-2-Hydroxy-1-isopropyl-pent-4-enyl)-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ((1S,2R)-2-Hydroxy-1-isopropyl-pent-4-enyl)-carbamic acid benzyl ester(123411-89-2)
• EPA Substance Registry System: ((1S,2R)-2-Hydroxy-1-isopropyl-pent-4-enyl)-carbamic acid benzyl ester(123411-89-2)

Safety Data

• Hazardous Substances Data: 123411-89-2(Hazardous Substances Data)

Upstream product

• 138754-84-4 N-benzyloxycarbonyl-L-valinal 
• 762-72-1 allyl-trimethyl-silane 
• 24210-19-3 methyl (2S)-3-methyl-[(benzyloxy)carbonylamino]butanoate 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 123411-93-8 (4S,5R)-5-allyl-4-isopropyloxazolidin-2-one 

Relevant articles and documents

A Novel BF3*OEt2-Catalyzed Annulation of N-Cbz-α-Amino Aldehides with Allyltrimethylsilane. Highly Stereoselective Synthesis of Cis-2,3,5-Trisubstituted Pyrrolidines

In the presence of BF3*OEt2 (0.2 molar equiv), the reactions (-10 deg C, CH2Cl2) of N-Cbz-α-amino aldehydes with allyltrimethylsilane produced pyrrolidines in good yields (70-80percent), with high all-cis stereoselectivity at the C-2, C-3, and C-5 positio