123492-27-3

Upstream product

• 89438-78-8 (-)-(S_P)-methylphenylvinylphosphine oxide 
• 98-84-0 D-α-phenylethylamine 
• 98-84-0 L-α-phenylethylamine 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 122768-21-2 Dimethyl-[2-((S)-methyl-phenyl-phosphinoyl)-ethyl]-amine 

Downstream Products

• 352007-12-6 (S_P,R_C)-PhCH(Me)NH(CH₂)2PPhMe 
• 883857-29-2 {2-[(R_P)-methylphenylphosphinoyl]ethyl}-(1S)-(1-phenylethyl)amine 

Relevant academic research and scientific papers

P-chiral β-aminophosphine oxides vs. β-aminophosphines as auxiliaries for ruthenium catalysed enantioselective transfer hydrogenation of arylketones

Enantiopure P-chiral β-aminophosphine oxides and the corresponding β-aminophosphines have been synthesised and used as chiral auxiliaries in ruthenium catalysed asymmetric transfer hydrogenation of arylketones producing optically active alcohols up to 80%

OPTICALLY ACTIVE PHOSPHINE OXIDES. 5. P-CHIRAL 2-AMINOETHYL PHOSPHINE OXIDES

Homochiral 2-aminoethyl phosphine oxides are expeditiously prepared by thermal addition of primary and secondary amines to (-)-(S)-methylphenylvinylphosphine oxide.Their transformation into optically active 2-aminoethyl phosphines and 2-aminoethyl phosphi