123641-61-2Relevant articles and documents
Transformations of quinic acid. Asymmetric synthesis and absolute configuration of mycosporin I and mycosporin-gly
White,Cammack,Sakuma,Rewcastle,Widener
, p. 3600 - 3611 (2007/10/02)
D-(-)-Quinic acid (1) was converted to the fungal metabolites mycosporin I (2) and mycosporin-gly (13) via the iminophosphorane 64. The latter was prepared in 10 steps from 1 using oxidative bromination of quinide 33 to furnish 41. Reduction of the γ-lact