123827-79-2Relevant academic research and scientific papers
Lactols in Stereoselection 3. Highly anti-Cram Selective 1,2-Asymmetric Induction
Tomooka, Katsuhiko,Okinaga, Tatsuyuki,Suzuki, Keisuke,Tsuchihashi, Gen-ichi
, p. 1563 - 1566 (1989)
Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner.The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.
