Tetrahedron Letters p. 1563 - 1566 (1989)
Update date:2022-07-31
Topics:
Tomooka, Katsuhiko
Okinaga, Tatsuyuki
Suzuki, Keisuke
Tsuchihashi, Gen-ichi
Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner.The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.
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