124-72-1Relevant academic research and scientific papers
Catalytic hydrogen-transfer reduction of polyhalofluoroalkanes using sodium hypophosphite
Hu, Chang-Ming,Tu, Ming-Hu
, p. 101 - 104 (1991)
The catalytic hydrogen-transfer reduction of polyhalofluoroalkanes using sodium hypophosphite in the presence of a platinum or palladium catalyst is described.A selective reduction of carbon-bromine bonds could be performed under mild conditions.
THE VIBRATIONAL SPECTRA OF 1-CHLORO-1-HYDRO-F-ETHANE, CF3CHFCl, AND 1-BROMO-1-HYDRO-F-ETHANE, CF3CHFBr
Noftle, R. E.,Ellis, Charles,Johnson, Gary,Bush, S. F.
, p. 29 - 42 (1984)
Infrared and Raman spectra were obtained for the fluorinated ethanes, CF3CHFCl and CF3CHFBr, and their deuterated isotopomers.A vibrational assignment of these molecules is reported.
Theoretical and experimental studies for preparing 1, 1-dibromo-1,2,2,2-tetrafluoroethane on gas-phase bromination of 1,1,1,2-tetrafluoroethane
Hu, Ruzhu,Zhang, Chengping,Qing, Feiyao,Quan, Hengdao
, p. 91 - 95 (2016/04/05)
Efficient gas-phase bromination of 1, 1, 1, 2-tetrafluoroethane (HFC-134a) for the preparation of 1, 1-dibromo-1, 2, 2, 2-tetrafluoroethane (CF3CFBr2) has been described for the first time. A wide-ranging experimental investigation o
A synthetic hexafluoro -1,3-butadiene method
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Paragraph 0034-0036; 0040; 0041, (2018/02/04)
The invention relates to a method for synthesizing hexafluoro-1,3-butadiene, and belongs to the field of organic chemistry synthesis. The method comprises the following steps: carrying out gas phase bromination on tetrafluoroethane HFC-134a to generate dibromotetrafluoroethane CF3CBr2F, and carrying out a coupling reaction on dibromotetrafluoroethane, activated zinc powder and N,N-dimethyl formamide under the action of Fe to generate hexafluoro-1,3-butadiene. A solvent after the above reactions can be recycled. The method has the advantages of low price and convenient source of raw materials, high product yield, simple separation and purification of the above product, and easy industrial production.
Pyrolytic decarboxylation of some derivatives of perfluorinated mono- and dicarboxylic acids
Lebedev,Berenblit,Starobin,Gubanov
, p. 1640 - 1645 (2007/10/03)
Pathways of pyrolysis of perfluorinated carboxylic acids are considered in relation to the structure of the acids and reaction conditions. The reaction mechanism is discussed.
