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1,1-Dibromotetrafluoroethane, commonly referred to as Halon 1202, is a chemical compound that was predominantly utilized in fire suppression systems. It is a liquefied gas, characterized by its non-conductive properties, colorless appearance, and heavier-than-air density, which allows it to effectively smother flames at ground level. Despite its high efficacy in fire suppression, the production of 1,1-Dibromotetrafluoroethane has been largely discontinued due to its significant ozone-depleting potential. As a result, it is typically found in older systems and is often replaced with more environmentally friendly alternatives during maintenance or decommissioning.

27336-23-8

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27336-23-8 Usage

Uses

Used in Fire Suppression Systems:
1,1-Dibromotetrafluoroethane is used as a fire suppressant in fire suppression systems for its ability to quickly smother flames at ground level. Its non-conductive and heavier-than-air properties make it an effective agent in controlling and extinguishing fires in various settings.
Used in Older Fire Suppression Systems:
1,1-Dibromotetrafluoroethane is found in older fire suppression systems, where it continues to serve its purpose until the system is serviced or decommissioned. Due to its environmental impact, it is being replaced with more eco-friendly alternatives in these systems.
Used in Environmentally Conscious Replacement:
As the production of 1,1-Dibromotetrafluoroethane has been phased out, it is used as a reference point for the development and implementation of more environmentally friendly fire suppression alternatives. This ensures that fire safety is maintained without compromising the ozone layer.

Check Digit Verification of cas no

The CAS Registry Mumber 27336-23-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,7,3,3 and 6 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 27336-23:
(7*2)+(6*7)+(5*3)+(4*3)+(3*6)+(2*2)+(1*3)=108
108 % 10 = 8
So 27336-23-8 is a valid CAS Registry Number.
InChI:InChI=1/C6H4BrFO/c7-5-3-4(9)1-2-6(5)8/h1-3,9H

27336-23-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,1-DIBROMOTETRAFLUOROETHANE

1.2 Other means of identification

Product number -
Other names 1,1-dibromospiropentane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:27336-23-8 SDS

27336-23-8Relevant academic research and scientific papers

Polymer chemistry. Part V. γ-Ray induced telomerisation reactions involving 1,1-difluoroethene and hexafluoropropene

Chambers, Richard D.,Proctor, Lee D.,Caporiccio, Gerardo

, p. 241 - 248 (1995)

Telomerisation reactions have been investigated for the alkenes 1,1-difluoroethene (5) and hexafluoropropene (3) with the telogens CF2Br2 (1), CF3CFBr2 (8) and CF3CBr3 (9), as a means of preparing telomers and co-telomers.The efficiency of chain transfer increases as 1 /= 8 9.Surprinsingly, co-telomerisations of 5 with 3 occurred more efficiently than the corresponding telomerisations with 5 alone.The effects of solvent are described. - Keywords: Telomerisation; γ-Ray induction; 1,1,-Difluoroethene; Hexafluoropropene; NMR spectroscopy; Mass spectrometry

A synthetic hexafluoro -1,3-butadiene method

-

Paragraph 0034-0036; 0040; 0041, (2018/02/04)

The invention relates to a method for synthesizing hexafluoro-1,3-butadiene, and belongs to the field of organic chemistry synthesis. The method comprises the following steps: carrying out gas phase bromination on tetrafluoroethane HFC-134a to generate dibromotetrafluoroethane CF3CBr2F, and carrying out a coupling reaction on dibromotetrafluoroethane, activated zinc powder and N,N-dimethyl formamide under the action of Fe to generate hexafluoro-1,3-butadiene. A solvent after the above reactions can be recycled. The method has the advantages of low price and convenient source of raw materials, high product yield, simple separation and purification of the above product, and easy industrial production.

Theoretical and experimental studies for preparing 1, 1-dibromo-1,2,2,2-tetrafluoroethane on gas-phase bromination of 1,1,1,2-tetrafluoroethane

Hu, Ruzhu,Zhang, Chengping,Qing, Feiyao,Quan, Hengdao

, p. 91 - 95 (2016/04/05)

Efficient gas-phase bromination of 1, 1, 1, 2-tetrafluoroethane (HFC-134a) for the preparation of 1, 1-dibromo-1, 2, 2, 2-tetrafluoroethane (CF3CFBr2) has been described for the first time. A wide-ranging experimental investigation o

Pyrolytic decarboxylation of some derivatives of perfluorinated mono- and dicarboxylic acids

Lebedev,Berenblit,Starobin,Gubanov

, p. 1640 - 1645 (2007/10/03)

Pathways of pyrolysis of perfluorinated carboxylic acids are considered in relation to the structure of the acids and reaction conditions. The reaction mechanism is discussed.

Comparison of the Reactivity of CF3OX (X = Cl, F) with Some Simple Alkenes

Johri, Kamalesh K.,DesMarteau, Darryl D.

, p. 242 - 250 (2007/10/02)

Reactions of CF3OX (X = Cl, F) with a variety of simple alkenes were carried out to compare the regio- and stereoselectivity of the additions to carbon-carbon double bonds.The observed addition products with CF3OCl are consistent with an electrophilic syn addition.With CF3OF the observed products indicate a different regioselectivity and low stereoselectivity, consistent with a free-radical addition.

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