124022-28-2

Upstream product

• 113161-31-2 3-benzyl-1,5-(dihydroxymethyl)-9-methylene-3-azabicyclo<3.3.1>nonane 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 

Downstream Products

• 113161-31-2 3-benzyl-1,5-(dihydroxymethyl)-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124022-29-3 Acetic acid (1S,5R)-3-benzyl-5-hydroxymethyl-9-methylene-3-aza-bicyclo[3.3.1]non-1-ylmethyl ester 
• 124097-07-0 (-)-(1R,5S)-1-(acetoxymethyl)-3-benzyl-5-hydroxymethyl-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124022-31-7 (-)-(1R,5S)-5-(acetoxymethyl)-3-benzyl-1-formyl-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124022-33-9 (-)-(1R,5S)-5-(acetoxymethyl)-3-benzyl-1-<((methoxymethyl)oxy)methyl>-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124022-26-0 (+)-(1S,5S)-3-benzyl-5-<(1'S,4'R)-((camphorsulfonyl)oxy)methyl>-1-methylene-3-azabicyclo<3.3.1>nonane 
• 124022-32-8 (-)-(1S,5S)-3-benzyl-5-(hydroxymethyl)-1-methyl-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124097-12-7 (+)-(1R,5R)-3-benzyl-1-(hydroxymethyl)-5-methyl-9-methylene-3-azabicyclo<3.3.1>nonane 
• 124150-10-3 (E)-(-)-(1R,5R,9R)-3-(methoxycarbonyl)-1-<((methoxymethyl)oxy)methyl>-9-(2-methoxystyryl)-5-methyl-3-azabicyclo<3.3.1>nonane 
• 124097-18-3 (-)-(1S,5R,9R)-1-(2-(methoxycarbonyl)ethenyl)-3-(methoxycarbonyl)-5-methyl-9-<2'-<1''-(2''-oxo)cyclohex-3''-enyl>ethyl>-3-azabicyclo<3.3.1>nonane 
• 124022-38-4 (1R,5R,9R)-1-((E)-2-Methoxycarbonyl-vinyl)-5-methyl-9-[2-(6-oxo-cyclohex-1-enyl)-ethyl]-3-aza-bicyclo[3.3.1]nonane-3-carboxylic acid methyl ester 
• 124022-42-0 (1R,5R,9R)-1-Formyl-5-methyl-9-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-3-aza-bicyclo[3.3.1]nonane-3-carboxylic acid methyl ester 
• 124022-36-2 (E)-(-)-(1R,5R,9R)-1-(hydroxymethyl)-3-(methoxycarbonyl)-9-(2-methoxystyryl)-5-methyl-3-azabicyclo<3.3.1>nonane 
• 124022-43-1 (1R,5R,9R)-1-Formyl-5-methyl-9-[2-(6-oxo-cyclohex-1-enyl)-ethyl]-3-aza-bicyclo[3.3.1]nonane-3-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Preparation of Chiral Building Blocks for Synthesis of Aconitium Alkaloids

Treatment of meso-diols 3 and 6 with CCL and vinyl acetate without solvent produced the AE part of Aconitium alkaloids 2 and 7 in 68percent and 75percent yields, respectively, with > 96percent e.e.Quantitative formations of their MTPA esters 4 and 8 were

Asymmetric total synthesis of atisine via intramolecular double Michael reaction

The bridged, pentacyclic intermediate 2 for atisine (1) was synthesized in a naturally occurring enantiomeric form from dimethyl cyclohexanone-2,6-dicarboxylate (6). The synthesis is composed of the following key steps: (1) formation of the azabicyclo[3.3