1240492-11-8

Basic information

• Product Name: (Z)-C₆H₅CHCHCH₂OP(O-2-ethylhexyl)2O
• Synonyms: (Z)-C₆H₅CHCHCH₂OP(O-2-ethylhexyl)2O
• CAS NO: 1240492-11-8
• Molecular Weight: 438.588
• Mol File: 1240492-11-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-C₆H₅CHCHCH₂OP(O-2-ethylhexyl)2O(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-C₆H₅CHCHCH₂OP(O-2-ethylhexyl)2O(1240492-11-8)
• EPA Substance Registry System: (Z)-C₆H₅CHCHCH₂OP(O-2-ethylhexyl)2O(1240492-11-8)

Safety Data

• Hazardous Substances Data: 1240492-11-8(Hazardous Substances Data)

Upstream product

• 63449-80-9 bis(2-ethylhexyl) phosphorochloridate 
• 4510-34-3 (Z)-cinnamyl alcohol 

Downstream Products

• 1240492-43-6 4,4,5,5-tetramethyl-2-[(1R,2R)-2-phenylcyclopropyl]-1,3,2-dioxaborolane 
• 1240492-43-6 (1S,2S)-4,4,5,5-tetramethyl-2-(2-phenylcyclopropyl)-1,3,2-dioxaborolane 
• 902757-46-4 4,4,5,5-tetramethyl-2-(2-phenylcyclopropyl)-1,3,2-dioxaborolane 

Relevant articles and documents

Enantioselective synthesis of trans-aryl-and-heteroaryl-substituted cyclopropylboronates by copper (I)-catalyzed reactions of allylic phosphates with a diboron derivative

A new asymmetric route for the synthesis of trans-2-aryl- and -heteroaryl-substituted cyclopropylboronates has been developed. (Z)-3-arylallylic phosphates were converted to the optically active products with high yield and diastereo- and enantioselectivity through a copper(I)-catalyzed reaction with a diboron derivative. Under mild reaction conditions, the reaction affords the arylcyclopropane products with a functional group and a heteroaromatic group in a highly enantioselective manner. When (E)-allylic phosphates were used as substrates, a ligand-controlled product switch between the trans and cis configurations was observed.