12411-25-5Relevant academic research and scientific papers
New experimental results and improvement of the modelization of the (Ga,Mg) system
Notin,Belbacha,Charles,Hertz
, p. 25 - 38 (1991)
Differential enthalpic analysis gave solidus and liquidus lines of the phase diagram. MgGa melts congruently; Mg2Ga is a stoichiometric compound; MgGa2 melts incongruently. The melting enthalpies of all the compounds were measured. A new numerical optimization of the thermodynamic properties was established using the NANCYUN program (Legendre polynomials), with all the known data. A consistent set of values in agreement with all the data (except one) is presented.
Li14.7Mg36.8Cu21.5Ga66: An intermetallic representative of a type IV clathrate
Lin, Qisheng,Corbett, John D.
, p. 10825 - 10831 (2008)
Synthetic explorations in the quaternary Li-Mg-Cu-Ga system yield the novel intermetallic Li14.7(8)Mg36.8(13)Cu 21.5(5)Ga66 [P6m2, Z = 1, a = 14.0803(4) A, c = 13.6252 (8) A] from within a limited composition range. This contains a unique three-dimensional anionic framework consisting of distinct interbonded Ga12 icosahedra, dimerized Li@(Cu,Mg)10Ga6 icosioctahedra, and 15-vertex Li@(Cu,Mg)9Ga6 and Li@Cu3Ga12 polyhedra. These polyhedral clusters are hosted by M20 (512), M24 (5126 2), and M26 (51263) (M = Li/Mg) cages, respectively. The geometries and arrangements of these cages follow those in known type IV clathrate hydrates.
YMgGa as a hydrogen storage compound
Sahlberg, Martin,Zlotea, Claudia,Moretto, Pietro,Andersson, Yvonne
, p. 1833 - 1837 (2009)
The hydrogen absorption and desorption properties of the recently found ternary phase YMgGa have been studied. This compound absorbs 2.2 wt% hydrogen during the first cycle, but only 1.1 wt% can be stored reversibly for the following cycles under the appl
