124160-41-4

Usage

Uses

Used in Organic Chemistry:
(2-(phenylethynyl)phenyl)boronic acid is used as a reagent for the synthesis of various organic compounds, taking advantage of its ability to form reversible covalent bonds with diols. Its unique structure allows for the creation of complex organic structures through cross-coupling reactions.
Used in Suzuki Coupling Reactions:
In the field of cross-coupling reactions, (2-(phenylethynyl)phenyl)boronic acid is used as a key component in Suzuki coupling reactions. This palladium-catalyzed reaction facilitates the formation of carbon-carbon bonds between an organoboronic acid and an organohalide or triflate, enabling the synthesis of a wide range of organic molecules.
Used in Medicinal Chemistry:
(2-(phenylethynyl)phenyl)boronic acid is utilized in medicinal chemistry for the development of pharmaceutical compounds. Its ability to form reversible covalent bonds with diols makes it a valuable building block for the creation of bioactive molecules with potential therapeutic applications.
Used in Materials Chemistry:
In materials chemistry, (2-(phenylethynyl)phenyl)boronic acid is employed in the synthesis of advanced materials with specific properties. Its unique structure and reactivity contribute to the development of materials with tailored characteristics for various applications, such as sensors, catalysts, and functional coatings.

Upstream product

• 536-74-3 phenylacetylene 
• 121-43-7 Trimethyl borate 
• 21375-88-2 1-bromo-2-(phenylethenyl)benzene 
• 7732-18-5 water 
• 5419-55-6 Triisopropyl borate 
• 54737-46-1 2,α,α'-tribromo-bibenzyl 
• 583-55-1 1-Bromo-2-iodobenzene 

Relevant academic research and scientific papers

Efficient access to alkynylated quinalizinones: Via the gold(i)-catalyzed aminoalkynylation of alkynes

The gold-catalyzed aminoalkynylation of alkynes for the synthesis of quinalizinones is reported. For instance, the reaction of pyridinoalkynes with 1-[(triisopropylsilyl)-ethynyl]-1,2-benziodoxol-3(1H)-one (TIPS-EBX) in the presence of a catalytic amount

Metal-Free Aminoiodination of Alkynes Under Visible Light Irradiation for the Construction of a Nitrogen-Containing Eight-Membered Ring System

A method for the synthesis of dihydrodibenzo[c,e]azocine derivatives via a regioselective intramolecular aminoiodination of alkynes under visible light irradiation has been developed. This protocol uses a combination of iodine and hypervalent iodine to re

Pyrene derivatives having substituted groups and organic light-emitting diode including the same

The present invention relates to a novel compound and an organic electroluminescent device comprising the same as luminous substances, and more specifically, to a novel compound represented by formula A or formula B and an organic electroluminescent device comprising the same.

Enantioselective Synthesis of 1,12-Disubstituted [4]Helicenes

A highly enantioselective synthesis of 1,12-disubstituted [4]carbohelicenes is reported. The key step for the developed synthetic route is a Au-catalyzed intramolecular alkyne hydroarylation, which is achieved with good to excellent regio- and enantioselectivity by employing TADDOL-derived (TADDOL=α,α,α,α-tetraaryl-1,3-dioxolane-4,5-dimethanol) α-cationic phosphonites as ancillary ligands. Moreover, an appropriate design of the substrate makes the assembly of [4]helicenes of different substitution patterns possible, thus demonstrating the synthetic utility of the method. The absolute stereochemistry of the newly prepared structures was determined by X-ray crystallography and characterization of their photophysical properties is also reported.

New compounds and organic light-emitting diode including the same

PURPOSE: A compound is provided to improve driving voltage and luminous efficiency of an organic electroluminescence device by having excellent light-emitting performance. CONSTITUTION: A compound is represented by chemical formula 1. An organic electroluminescence device comprises an anode, a cathode, and an electroluminescent layer comprising the compound and inserted between the anode and the cathode. The organic electroluminescence device additionally comprises one or more layers selected form a hole injection layer, a hole transport layer, an electro block layer, a hole block layer, an electron transport layer and an electron injection layer. The one or more layers are formed by a monomer deposition method or solution process.

Pyrene derivatives having substituted groups and organic light-emitting diode including the same

The present invention relates to a novel compound and an organic electroluminescent device including the same as luminous substances, and more specifically, to a novel compound represented by formula A or formula B and an organic electroluminescent device

Pyrene derivative compounds and organic light-emitting diode including the same

PURPOSE: A pyrene derivative compound is provided to provide an organic electroluminescence device operable at low voltage and having improved luminous efficiency by having stable and excellent luminous properties. CONSTITUTION: A pyrene derivative compound is represented by chemical formula 1-5. An organic electroluminescence device comprises an anode, a cathode, an electroluminescent layer comprising the compound and inserted between the anode and the cathode. Between the anode and the cathode, one or more layers selected from a hole injection layer, a hole transport layer, an electron block layer, a hole block layer, an electron transport layer and an electron injection layer. The one or more layers are formed by a monomer evaporation method of a solution process.

Pyrene derivatives having substituted cyclic amine groups and organic light-emitting diode including the same

The present invention relates to a novel compound and an organic electroluminescent device comprising the same as luminous substances, and more specifically, to a novel compound represented by formula A or formula B and an organic electroluminescent device comprising the same.

New compounds and organic light-emitting diode including the same

PURPOSE: A fused aryl compound is provided to be stable and to have excellent luminous efficiency, thereby capable of providing an organic electroluminescence device with excellent driving voltage, external quantum efficiency, color purity and life time performance. CONSTITUTION: A fused aryl compound is represented by chemical formula 1. In chemical formula 1, each of R is selected from hydrogen, deuterium, substituted or unsubstituted C1-6 alkyl, substituted or unsubstituted C7-30, substituted or unsubstituted C3-30 cycloalkyl, substituted or unsubstituted C5-30 cycloalkenyl, substituted or unsubstituted C1-30 alkoxy, substituted or unsubstituted C6-30 aryloxy, substituted or unsubstituted C1-30 alkylthioxy, substituted or unsubstituted C5-30 arylthioxy, substituted or unsubstituted C1-30 alkylamine, substituted or unsubstituted C5-30 arylamine, substituted or unsubstituted C5-50 aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted silicon, substituted or unsubstituted boron, substituted or unsubstituted silane, carbonyl, phosphoryl, amino, nitrile, hydroxy, nitro, halogen, amide, and ester.

Controlling the Selectivity Patterns of Au-Catalyzed Cyclization-Migration Reactions

As little as 2 mol % of (XPhos)AuNTf2 catalyzes the transformation of a broad range of o-acetylene-substituted styrenes into 1,2-dihydronaphthalenes. Our data suggests that this transformation occurs via a gold-stabilized cyclopropyl carbinyl cation, which triggers either a [1,2] carboxylate shift or a less favorable [1,2] aryl shift. The relative rates of these migrations can be controlled by the identity of the ligand or by stabilizing the mesomeric cation.