124175-90-2Relevant academic research and scientific papers
Synthesis of Functionalized Azomethine Ylides via the Rh(II)-Catalyzed Cyclization of α-Diazo Carbonyls onto Imino ?-Bonds
Padwa, Albert,Dean, Dennis C.,Osterhout, Martin H.,Precedo, Laura,Semones, Mark A.
, p. 5347 - 5357 (2007/10/02)
α-Diazo carbonyl compounds containing an imino group in the γ-position have been found to undergo a rhodium(II) acetate induced cyclization reaction to generate cyclic azomethine ylides.The reactive dipole undergoes a subsequent 1,3-dipolar cycloaddition
Azomethine Ylide Generation via the Rhodium(II)-Induced Cyclization Reaction of Oximino α-Diazo Ketones
Padwa, Albert,Dean, Dennis C.
, p. 405 - 406 (2007/10/02)
The rhodium(II)-catalyzed reaction of α-diazo ketones with a neighboring oxime ether generates cyclic azomethine ylides which undergo ready 1,3-dipolar cycloaddition.
