86492-76-4Relevant academic research and scientific papers
Azomethine Ylide Generation via the Rhodium(II)-Induced Cyclization Reaction of Oximino α-Diazo Ketones
Padwa, Albert,Dean, Dennis C.
, p. 405 - 406 (1990)
The rhodium(II)-catalyzed reaction of α-diazo ketones with a neighboring oxime ether generates cyclic azomethine ylides which undergo ready 1,3-dipolar cycloaddition.
Tandem double acylation/[3,3]-rearrangement of aliphatic nitro compounds: A route to α-oxygenated oxime derivatives
Antonova, Yulia A.,Nelyubina, Yulia V.,Sukhorukov, Alexey Yu.,Ioffe, Sema L.,Tabolin, Andrey A.
, p. 5997 - 6006 (2019/06/24)
A new tandem double acylation/rearrangement reaction of nitro compounds is described. It has a broad substrate scope allowing the mild and efficient synthesis of α-acyloxy oxime esters in high yields and regioselectivity. According to the obtained data, the mechanism for transformation was proposed. The utility of the obtained α-hydroxy oxime esters was demonstrated.
Synthesis of 4,5-dihydroisoxazoles by condensation of primary nitro compounds with alkenes by using a copper/base catalytic system
Cecchi, Luca,De Sarlo, Francesco,Machetti, Fabrizio
experimental part, p. 7903 - 7912 (2009/09/06)
A new procedure for the synthesis of 4.5-dihydroisoxazoles by condensation of primary nitro compounds with olefins by using a copper/base catalytic system is described. The catalytic effect of copper(II) salts is evidenced by comparison of the reaction ra
