124306-11-2

Basic information

• Product Name: Silane, trimethyl[[(1Z)-1-phenyl-1,3-butadienyl]oxy]-
• CAS NO: 124306-11-2
• Molecular Formula: C13H18OSi
• Molecular Weight: 218.371
• Mol File: 124306-11-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[(1Z)-1-phenyl-1,3-butadienyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[(1Z)-1-phenyl-1,3-butadienyl]oxy]-(124306-11-2)
• EPA Substance Registry System: Silane, trimethyl[[(1Z)-1-phenyl-1,3-butadienyl]oxy]-(124306-11-2)

Safety Data

• Hazardous Substances Data: 124306-11-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 495-41-0 1-phenylbut-2-en-1-one 
• 5908-41-8 benzoyltrimethylsilane 
• 19093-37-9 allyl phenyl sulfoxide 

Downstream Products

• 73311-68-9 1-Phenyl-2-phenylsulfanylmethyl-but-3-en-1-one 
• 73311-69-0 (E)-1-Phenyl-5-phenylsulfanyl-pent-2-en-1-one 
• 73311-70-3 1-Phenyl-3-phenylsulfanyl-2-vinyl-hexan-1-one 
• 73311-71-4 (E)-1-Phenyl-5-phenylsulfanyl-oct-2-en-1-one 
• 1192712-77-8 2-((2S,4R,6R)-4-hydroxy-6-phenyltetrahydro-2H-pyran-2-yl)-1-phenylethan-1-one 
• 77987-28-1 (E)-5,5-Dimethoxy-1-phenyl-pent-2-en-1-one 
• 85920-98-5 (E)-6-Oxo-6-phenyl-2-phenylsulfanyl-hex-4-enoic acid methyl ester 
• 147032-71-1 1-phenyl-hept-2-ene-1,6-dione 
• 77987-25-8 (E)-5-Ethoxy-1-phenyl-hex-2-en-1-one 
• 77987-30-5 2-(1-Ethoxy-ethyl)-1-phenyl-but-3-en-1-one 
• 77987-24-7 (E)-5-methoxy-1-phenylpent-2-en-1-one 
• 77987-29-2 2-Methoxymethyl-1-phenyl-but-3-en-1-one 

Relevant articles and documents

Asymmetric synthesis of rauhut-currier type products by a regioselective mukaiyama reaction under bifunctional catalysis

The reactivity and the regioselective functional-ization of silyl-diene enol ethers under a Afunctional organocatalyst provokes a dramatic change in the regioselectiv-ity, from the 1, 5- to the 1, 3-functionalization. This variation makes possible the 1, 3-addition of silyl-dienol ethers to nitroalkenes, giving access to the synthesis of tri- and tetrasubstituted double bonds in Rauhut-Currier type products. The process takes place under smooth conditions, nonanionic conditions, and with a high enantiomeric excess. A rational mechanistic pathway is presented based on DFT and mechanistic experiments.

Asymmetric vinylogous Mukaiyama aldol reaction of isatins under bifunctional organocatalysis: Enantioselective synthesis of substituted 3-hydroxy-2-oxindoles

A highly enantioselective organocatalytic vinylogous Mukaiyama aldol reaction of silyloxy dienes and isatins under bifunctional organocatalysis is presented. Substituted 3-hydroxy-2-oxindoles are synthesised in good yields and enantioselectivities. These

Reaction of acylsilanes with α-sulfinyl carbanions: Regioselective synthesis of silyl enol ethers

The reaction of acylsilanes with α-sulfinyl carbanions such as α-lithioalkyl sulfoxide is described. The reaction proceeds to give silyl enol ethers preferentially through the initial formation of the α-silyl alkoxide intermediates. In particular, the products derived from enolizable acylsilanes were the regio-defined silyl enol ethers that cannot be obtained by usual enolization of the corresponding unsymmetrical ketones with base.