124477-15-2

Basic information

• Product Name: 1,5-anhydro-3-O-benzyl-2,6-dideoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-D-arabino-hex-1-enitol
• Synonyms: 1,5-anhydro-3-O-benzyl-2,6-dideoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-D-arabino-hex-1-enitol
• CAS NO: 124477-15-2
• Molecular Weight: 530.661
• Mol File: 124477-15-2.mol

Chemical Properties

• CAS DataBase Reference: 1,5-anhydro-3-O-benzyl-2,6-dideoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-D-arabino-hex-1-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-anhydro-3-O-benzyl-2,6-dideoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-D-arabino-hex-1-enitol(124477-15-2)
• EPA Substance Registry System: 1,5-anhydro-3-O-benzyl-2,6-dideoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-D-arabino-hex-1-enitol(124477-15-2)

Safety Data

• Hazardous Substances Data: 124477-15-2(Hazardous Substances Data)

Upstream product

• 124477-14-1 phenyl 2,3-di-O-benzyl-6-deoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexapyranosyl)-1-thio-β-D-glucopyranoside 

Downstream Products

• 129081-23-8 methyl O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-(1->4)-O-(3-O-benzyl-2,6-dideoxy-2-phenylseleno-α-D-mannopyranosyl)-(1->4)-O-(3-O-benzoyl-2,6-dideoxy-3-C-methyl-β-D-arabino-hexopyranosyl)-(1->3)-2-O-benzyl-4-O-methyl-β-D-galactopy.. 

Relevant articles and documents

CONVENIENT SYNTHESES OF SUBSTITUTED PYRANOID GLYCALS FROM THIOPHENYL GLYCOSIDES AND GLYCOSYL PHENYLSULFONES

A series of substituted thiophenyl glycosides and glycosyl phenylsulfones were converted in high yield into glycals after reductive lithiation with lithium naphthalenide, followed by elimination of the substituent at C-2.

PREPARATION OF PYRANOID GLYCAL DERIVATIVES FROM PHENYL THIOGLYCOSIDES AND GLYCOSYL PHENYL SULPHONES

Phenyl thioglycopyranosides with various protecting groups (acetal, ether, ester) underwent reductive lithiation at C-1, followed by rapid elimination of the 2-substituent, when treated with lithium naphthalenide in tetrahydrofuran at low temperature.Thus