CONVENIENT SYNTHESES OF SUBSTITUTED PYRANOID GLYCALS FROM THIOPHENYL GLYCOSIDES AND GLYCOSYL PHENYLSULFONES

DOI: 10.1016/S0040-4039(01)80444-5

Source and publish data:

Tetrahedron Letters p. 2537 - 2540 (1989)

Update date:2022-08-04

Topics: Experimental terms convenient syntheses

Authors:

Fernandez-Mayoralas, Alfonso

Marra, Alberto

Trumtel, Michel

Veyrieres, Alain

Sinay, Pierre

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Article abstract of DOI:10.1016/S0040-4039(01)80444-5

A series of substituted thiophenyl glycosides and glycosyl phenylsulfones were converted in high yield into glycals after reductive lithiation with lithium naphthalenide, followed by elimination of the substituent at C-2.

Full text of DOI:10.1016/S0040-4039(01)80444-5

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