124573-35-9Relevant academic research and scientific papers
Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones
Justik, Michael W.,Koser, Gerald F.
, p. 6159 - 6163 (2004)
The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.
A Convenient Synthesis of Some (1-Alkylethenyl)arenes and Bis(1-alkylethenyl)arenes
Blatter, Karsten,Schlueter, Arnulf-Dieter
, p. 356 - 359 (2007/10/02)
The title compounds may be prepared in good yields and high isomeric purities (98 + percent) by reaction of 1-alkylethenylmagnesium bromides with bromo- or dibromoarenes, respectively).An improved synthesis of 2,6-dibromonaphthalene and synthesis of 4,9-dibromopyrene are also described.
