51439-05-5Relevant academic research and scientific papers
Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones
Justik, Michael W.,Koser, Gerald F.
, p. 6159 - 6163 (2007/10/03)
The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.
NOVEL CONVERSION OF A KETONE DIMETHYL DITHIOACETAL S,S-DIOXIDE TO THE CORRESPONDING KETONE AND ITS APPLICATION TO SYNTHESIS OF ACYCLIC AND CYCLIC KETONES
Ogura, Katsuyuki,Suzuki, Michiyo,Watanabe, Jun-ichi,Yamashita, Mitsuo,Iida, Hirotada,Tsuchihashi, Gen-ichi
, p. 813 - 814 (2007/10/02)
A ketone dimethyl dithioacetal S,S-dioxide was easily hydrolyzed with hydrochloric acid in refluxing methanol and this transformation was applied to a new method for making acyclic and cyclic ketones by the use of formaldehyde dimethyl dithioacetal S,S-dioxide.
