Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones

DOI: 10.1016/j.tetlet.2004.06.029

Source and publish data:

Tetrahedron Letters p. 6159 - 6163 (2004)

Update date:2022-09-26

Topics:

Authors:

Justik, Michael W.

Koser, Gerald F.

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Article abstract of DOI:10.1016/j.tetlet.2004.06.029

The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.

Full text of DOI:10.1016/j.tetlet.2004.06.029

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