1245919-59-8Relevant articles and documents
Electrochemical synthesis of the aryl α-ketoesters from acetophenones mediated by Ki
Zhang, Zhenlei,Su, Jihu,Zha, Zhenggen,Wang, Zhiyong
, p. 17711 - 17714 (2013)
Two C-O bonds formed in one step: The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α-ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α-ketoester derivatives, but also invents a new strategy to construct a C-O bond by virtue of an anode oxidation (see scheme). Copyright
Rh-catalyzed asymmetric hydrogenation of racemic aldimines via dynamic kinetic resolution
Fan, Dongyang,Lu, Jian,Liu, Yang,Zhang, Zhenfeng,Liu, Yangang,Zhang, Wanbin
, p. 5541 - 5547 (2016/08/05)
Catalyzed by a rhodium complex of P-stereogenic diphosphine ligand trichickenfootphos (TCFP), asymmetric hydrogenation of racemic aldimines via dynamic kinetic resolution has been realized for the preparation of chiral arylglycines with good yields and enantioselectivities.
Palladium-catalyzed [4 + 2] cycloaddition of o-(silylmethyl)benzyl esters with ketones: An equivalent to oxo-diels-alder reaction of o-xylylenes
Ueno, Satoshi,Ohtsubo, Masakazu,Kuwano, Ryoichi
supporting information; experimental part, p. 4332 - 4334 (2010/12/19)
Figure Presented. o-(Silylmethyl)benzyl carbonates reacted with various electron-deficient ketones in the presence of a palladium catalyst, affording the [4 + 2] cycloaddition products, isochromanes, in high yields. The palladium-catalyzed cycloaddition i