124595-44-4

Upstream product

• 4551-15-9 phenylthiotrimethylsilane 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 10548-46-6 1,6-anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose 
• 120403-26-1 phenyl 2,3,4-tri-O-benzyl-1-thio-α-D-glucopyranoside 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 498-07-7 levoglucosan 
• 100-39-0 benzyl bromide 

Relevant academic research and scientific papers

Glycosylation of allyl 2-acetamido-4,6-O-benzylidene-2-deoxy-α-D- glucopyranoside with bulky substituted glycosyl donors

Glycosylation of allyl 2-acetamido-4,6-O-benzylidene-2-deoxy-α-D- glucopyranoside with bulky substituted glycosyl donors leads to the formation of derivatives of the disaccharide α-D-Glc-(1→3)-D-GlcNAc with different yields.

FACILE SYNTHESIS OF SILYLATED THIOGLYCOSIDES

The one pot conversion of 1,2,4,6-tetra-O-acetyl-β-D-glucopyranose, 1, into phenyl 2,4,6-tri O-acetyl-3-O-trialkylsilyl-1-thio-β-D-glucopyranosides, 3, is described.The method is applicable to use with galactopyranosyl-, 2-deoxyglucopyranosyl-, and ribofuranosyl-starting materials.