124603-50-5

Upstream product

• 589-92-4 1-methylcyclohexan-4-one 
• 127-65-1 chloroamine-T 
• 124603-50-5 trans-6-(4-methylphenylsulfonyl)amino-4-methyl-1-triisopropyl-silyl(oxy)-cyclohex-1-ene 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 125332-27-6 4-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 124603-56-1 6-(4-methylphenylsulfonyl)imino-4-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 60123-29-7 N,N'-di(p-tolylsulfonyl)selenium diimide 

Downstream Products

• 137963-68-9 cis-6-(4-methylphenylsulfonyl)amino-6-(trimethylsilylethyn)-4-methyl-1-triisopropyl silyl(oxy)-cyclohexene 
• 124603-59-4 2α-(4-methylphenylsulfonyl)amino-4β-methyl-6α-(3-chlorobenzoyloxy)-cyclohex-1-one 
• 124603-50-5 cis-6-(4-methylphenylsulfonyl)amino-4-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 124603-55-0 (1R,5S)-5-Methyl-2-triisopropylsilanyloxy-cyclohex-2-enylamine 
• 124603-58-3 4-Methyl-N-(5-methyl-2-triisopropylsilanyloxy-cyclohex-1-enyl)-benzenesulfonamide 

Relevant academic research and scientific papers

New Trialkylsilyl Enol Ether Chemistry: α-N-Tosylamination of Triisopropylsilyl Enol Ethers

Triisopropylsilyl enol ethers react with (TsN)2Se to give α-N-tosylamino derivatives in modest to good yields.In the absence of 1,3-diaxial interactions the N-tosylamino group prefers an axial conformation.The axial N-tosylamino derivatives can be readily transformed into the azabicyclononane skeleton, the core structure of a number of alkaloids.