1246523-44-3

Basic information

• Product Name: 2-azido-1-tert-butoxy-3-iodobenzene
• Synonyms: 2-azido-1-tert-butoxy-3-iodobenzene
• CAS NO: 1246523-44-3
• Molecular Weight: 317.129
• Mol File: 1246523-44-3.mol

Chemical Properties

• CAS DataBase Reference: 2-azido-1-tert-butoxy-3-iodobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-azido-1-tert-butoxy-3-iodobenzene(1246523-44-3)
• EPA Substance Registry System: 2-azido-1-tert-butoxy-3-iodobenzene(1246523-44-3)

Safety Data

• Hazardous Substances Data: 1246523-44-3(Hazardous Substances Data)

Upstream product

• 1493-27-2 ortho-nitrofluorobenzene 
• 127517-27-5 2-(tert-butoxy)aniline 
• 83747-12-0 2-(tert-butoxy)-1-nitrobenzene 
• 1246523-55-6 tert-butyl [2-(tert-butoxy)-6-iodophenyl]carbamate 
• 1246523-54-5 tert-butyl [2-(tert-butoxy)phenyl]carbamate 
• 1246523-56-7 tert-butyl 2-tert-butoxy-6-iodophenylcarbamate 

Downstream Products

• 1246523-45-4 methyl 2-(4-(2-azido-3-tert-butoxyphenyl)-6-methoxy-1-(4-methoxyphenethyl)-3,7-bis(4-methoxyphenyl)-1H-indol-2-yl)-2-(4-methoxyphenyl)acetate 
• 1246523-60-3 (4-(2-azido-3-(tert-butoxy)phenyl)-6-methoxy-1-(4-methoxyphenethyl)-3,7-bis(4-methoxyphenyl)-1H-indol-2-yl)(4-methoxyphenyl)methanone 
• 1310146-42-9 1-(4-(benzyloxy)phenethyl)-4-(3-tert-butoxy-2-azidophenyl)-6-methoxy-3,7-bis(4-methoxyphenyl)-1H-indole 
• 1310146-40-7 4-(2-azido-3-tert-butoxyphenyl)-6-methoxy-1-(4-methoxyphenethyl)-3,7-bis(4-methoxyphenyl)-1H-indole 
• 1269631-53-9 4-(2-azido-3-tert-butoxyphenyl)-6-methoxy-2-(4-methoxybenzyl)-1-(4-methoxyphenethyl)-3,7-bis(4-methoxyphenyl)-1H-indole 
• 1269631-73-3 sulfuric acid 1,4-bis-(4-hydroxy-phenyl)-2,5-dioxo-3-{2-[4-(2,2,2-trichloro-ethoxysulfonyloxy)-phenyl]-ethyl}-2,3,5,6-tetrahydro-pyrrolo[2,3-c]carbazol-7-yl ester 2,2,2-trichloro-ethyl ester 
• 1269631-70-0 Sulfuric acid 5-hydroxy-1,4-bis-(4-methoxy-phenyl)-3-{2-[4-(2,2,2-trichloro-ethoxysulfonyloxy)-phenyl]-ethyl}3,6-dihydro-pyrrolo[2,3-c]carbazol-7-yl ester 2,2,2-trichloro-ethyl ester 
• 1310146-45-2 3-(4-hydroxyphenethyl)-3,6-dihydro-5-methoxy-1,4-bis(4-methoxyphenyl)pyrrolo[2,3-c]carbazol-7-ol 
• 1269631-68-6 3-[4-(benzyloxy)phenethyl]-7-(tert-butoxy)-5-methoxy-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole 
• 901121-70-8 dictyodendrin C 
• 1269631-76-6 sulfuric acid 5-hydroxy-1,4-bis-(4-hydroxy-phenyl)-3-[2-(4-hydroxy-phenyl)-ethyl]-3,6-dihydropyrrolo[2,3-c]carbazol-7-yl ester 2,2,2-trichloro-ethyl ester 
• 1269631-74-4 7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole 
• 1269631-54-0 7-tert-butoxy-5-methoxy-2-(4-methoxybenzyl)-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole 
• 1246657-85-1 dictyodendrin A 

Relevant articles and documents

Total synthesis of dictyodendrins A-E

A highly efficient total synthesis of dictyodendrins A-E was accomplished. The synthesis features a novel benzyne-mediated one-pot indoline formation/cross-coupling sequence for the construction of a highly substituted key indoline intermediate. Peripheral substituents were introduced onto this intermediate in a modular fashion to complete the total synthesis of dictyodendrins A-E. A benzyne-mediated one-pot indoline formation/cross-coupling sequence is used for the construction of a highly substituted common indole intermediate. The peripheral substituents were introduced using a Friedel-Crafts reaction on the indole intermediate in a modular fashion to complete the total synthesis. Copyright

Total synthesis of dictyodendrin A and B

(Figure Presented) In-do-line of fire: A highly efficient total synthesis of the title compounds features a novel benzyne-mediated one-pot indoline formation/cross-coupling sequence for the construction of a highly substituted key indoline intermediate. The peripheral substituents were then introduced onto the intermediate in a modular fashion to complete the total syntheses of dictyodendrin A and B.