1246523-60-3

Upstream product

• 1246523-44-3 2-azido-1-tert-butoxy-3-iodobenzene 
• 1246523-59-0 (6-methoxy-1-(4-methoxyphenethyl)-3,7-bis(4-methoxyphenyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indol-2-yl)(4-methoxyphenyl)methanone 
• 127517-27-5 2-(tert-butoxy)aniline 
• 123-11-5 4-methoxy-benzaldehyde 
• 1493-27-2 ortho-nitrofluorobenzene 
• 100-07-2 4-methoxy-benzoyl chloride 
• 886762-71-6 1-fluoro-3-iodo-2-nitrobenzene 
• 83747-12-0 2-(tert-butoxy)-1-nitrobenzene 
• 3179-10-0 (E)-1-methoxy-4-(2-nitrovinyl)benzene 
• 702-23-8 2-(4-Methoxyphenyl)ethanol 
• 14425-64-0 4-methoxyphenethyl bromide 
• 1246523-41-0 4-bromo-6-methoxy-3,7-bis-(4-methoxy-phenyl)-2,3-dihydro-indole-1-carboxylic acid tert-butyl ester 
• 1246523-40-9 1-(1-(2,6-dibromo-4-methoxyphenyl)-2-nitroethyl)-4-methoxybenzene 

Downstream Products

• 1246523-61-4 (7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazol-2-yl)(4-methoxyphenyl)methanone 
• 864816-28-4 {7-hydroxy-5-methoxy-1,4-bis-(4-methoxyphenyl)-3-[2-(4-methoxyphenyl)ethyl]-3,6-dihydropyrrolo[2,3-c]carbazol-2-yl}-(4-methoxyphenyl)methanone 
• 864816-29-5 sulfuric acid 5-methoxy-2-(4-methoxybenzoyl)-1,4-bis-(4-methoxyphenyl)-3-[2-(4-methoxyphenyl)ethyl]-3,6-dihydropyrrolo[2,3-c]carbazol-7-yl ester 2,2,2-trichloroethyl ester 
• 900504-65-6 5-methoxy-2-(4-methoxybenzyl)-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazol-7-ol 
• 900504-66-7 5-methoxy-2-(4-methoxybenzyl)-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazol-7-yl 2,2,2-trichloroethyl sulfate 
• 900504-67-8 5-hydroxy-2-(4-hydroxybenzyl)-3-(4-hydroxyphenethyl)-1,4-bis(4-hydroxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazol-7-yl 2,2,2-trichloroethyl sulfate 
• 1269631-54-0 7-tert-butoxy-5-methoxy-2-(4-methoxybenzyl)-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole 

Relevant academic research and scientific papers

A concise and scalable strategy for the total synthesis of dictyodendrin B based on sequential C-H functionalization

A sequential C-H functionalization strategy for the synthesis of the marine alkaloid dictyodendrin B is reported. Our synthesis begins from commercially available 4-bromoindole and involves six direct functionalizations around the heteroarene core as part of a gram-scale strategy towards the natural product.

Total synthesis of dictyodendrins A-E

A highly efficient total synthesis of dictyodendrins A-E was accomplished. The synthesis features a novel benzyne-mediated one-pot indoline formation/cross-coupling sequence for the construction of a highly substituted key indoline intermediate. Peripheral substituents were introduced onto this intermediate in a modular fashion to complete the total synthesis of dictyodendrins A-E. A benzyne-mediated one-pot indoline formation/cross-coupling sequence is used for the construction of a highly substituted common indole intermediate. The peripheral substituents were introduced using a Friedel-Crafts reaction on the indole intermediate in a modular fashion to complete the total synthesis. Copyright

Total synthesis of dictyodendrin A and B

(Figure Presented) In-do-line of fire: A highly efficient total synthesis of the title compounds features a novel benzyne-mediated one-pot indoline formation/cross-coupling sequence for the construction of a highly substituted key indoline intermediate. The peripheral substituents were then introduced onto the intermediate in a modular fashion to complete the total syntheses of dictyodendrin A and B.