124718-81-6

Basic information

• Product Name: phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside
• Synonyms: phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside
• CAS NO: 124718-81-6
• Molecular Weight: 510.63
• Mol File: 124718-81-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(124718-81-6)
• EPA Substance Registry System: phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(124718-81-6)

Safety Data

• Hazardous Substances Data: 124718-81-6(Hazardous Substances Data)

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 108-95-2 phenol 
• 3262-89-3 triphenylboroxine 
• 160549-11-1 3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranose 
• 135192-39-1 phenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 135192-44-8 phenyl 3,4,6-tri-O-benzyl-2-O-<(pentafluorophenoxy)thiocarbonyl>-β-D-glucopyranoside 
• 124718-63-4 phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside 

Relevant articles and documents

Copper-mediated anomeric: O -arylation with organoboron reagents

Copper-mediated couplings of arylboroxines with glycosyl hemiacetals furnish O-aryl glycosides via Csp2-O bond formation. The method enables the anomeric O-arylation of protected pyranose and furanose derivatives, and is tolerant of functionalized arylboroxine partners. Whereas mixtures of anomers are formed from glucopyranose, galactopyranose and arabinofuranose hemiacetals, the α-anomer is generated selectively from mannopyranose and mannofuranose-derived substrates.

Reagent controlled β-specific dehydrative glycosylation reactions with 2-deoxy-sugars

N-Sulfonyl imidazoles activate 2-deoxy-sugar hemiacetals for glycosylation presumably by converting them into glycosyl sulfonates in situ. By matching the leaving group ability of the sulfonate with the reactivity of the donor, it is possible to obtain β-

A stereospecific route to 2-deoxy-β-glycosides

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