135192-39-1

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 108-95-2 phenol 
• 98-80-6 phenylboronic acid 
• 51532-75-3 3,4,6-tri-O-benzyl-1,2-O-(1-methoxyethylidene)-α-D-glucopyranose 
• 138925-14-1 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside 

Downstream Products

• 138925-05-0 phenyl O-(2-deoxy-2-iodo-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1-2)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 144427-74-7 phenyl 3,4,6-tri-O-benzyl-2-O-(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-ribo-hexopyranosyl)-β-D-glucopyranoside 
• 135192-44-8 phenyl 3,4,6-tri-O-benzyl-2-O-<(pentafluorophenoxy)thiocarbonyl>-β-D-glucopyranoside 
• 138925-10-7 Benzoic acid (1R,5R,7S,8S,9S)-9-iodo-1,7-dimethyl-3-phenyl-4,6-dioxa-2-aza-bicyclo[3.3.1]non-2-en-8-yl ester 
• 138925-12-9 phenyl O-(3-benzamido-4-O-benzoyl-2,3,6-tri-O-trideoxy-3-C-methyl-α-L-lyxo-hexopyranosyl)-(1-2)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 124718-81-6 phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 144427-75-8 phenyl 3,4,6-tri-O-benzyl-2-O-(2,3,6-trideoxy-3-trifluoroacetamido-α-L-ribohexopyranosyl)-β-D-glucopyranoside 
• 144427-76-9 phenyl 3,4,6-tri-O-acetyl-2-O-(3-trifluoroacetamido-4-O-acetyl-2,3,6-trideoxy-α-L-ribohexopyranosyl)-β-D-glucopyranoside 
• 138925-14-1 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 138925-07-2 phenyl O-(2-deoxy-3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-2)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Tunable stereoselectivity in the synthesis of α- and β-aryl glycosides using 1,2-α-anhydrosugars as glycosyl donors

The stereochemical course of O-glycosidation of 1,2-α-D-anhydrosugars (glycal epoxides) with phenols can be tuned by varying the metal ion of the base. While the reaction of 1,2-α-D-anhydrosugars with phenols mediated by trimethylaluminium leads exclusive

Simple and mild stereoselective O-glycosidation using 1,2-anhydrosugars under neutral conditions

The ring opening of α-D-1,2-anhydrohexapyranoses with phenols proceeded smoothly in ethyl acetate (neutral conditions) in the absence of metal ion catalysts or additives to stereoselectively furnish 1,2-cis-α-aryl glycosides as the major product and 1,2-t

KOtBu-mediated aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acid

A new approach for the synthesis of phenolic glycosides via aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acids was disclosed. This method is characterized by the use of aryl boronic acid as the aryl source and produces phenolic glycosides

Synthesis of a phenyl β-avobioside derivative of the disaccharide component of avoparcins

The synthesis of the phenyl β-glycoside of avobiose, a disaccharide fragment present in the antibiotic avoparcin, is reported. It is based on glycosylation of phenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside with 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoro

Stereospecific synthesis of aryl β-glucosides: An application to the synthesis of a prototype corresponding to the aryloxy carbohydrate domain of vancomycin

The reaction of 3,4,6-tri-O-benzyl-D-glucal (2) with 3,3-dimethyldioxirane gives rise to the 2α,3α-oxirane with high stereoselection. Reaction of this compound with various phenols under alkaline conditions affords aryl 2α-hydroxy-β-glycosides (3a-d). Oxi