135192-39-1Relevant articles and documents
Tunable stereoselectivity in the synthesis of α- and β-aryl glycosides using 1,2-α-anhydrosugars as glycosyl donors
Somasundaram, Devaraj,Balasubramanian, Kalpattu K.,Bhagavathy, Shanmugasundaram
, p. 95 - 102 (2017)
The stereochemical course of O-glycosidation of 1,2-α-D-anhydrosugars (glycal epoxides) with phenols can be tuned by varying the metal ion of the base. While the reaction of 1,2-α-D-anhydrosugars with phenols mediated by trimethylaluminium leads exclusive
KOtBu-mediated aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acid
Liu, Chen-Fu,Xiong, De-Cai,Ye, Xin-Shan
supporting information, p. 1372 - 1374 (2018/03/29)
A new approach for the synthesis of phenolic glycosides via aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acids was disclosed. This method is characterized by the use of aryl boronic acid as the aryl source and produces phenolic glycosides
Stereospecific synthesis of aryl β-glucosides: An application to the synthesis of a prototype corresponding to the aryloxy carbohydrate domain of vancomycin
Dushin, Russell G.,Danishefsky, Samuel J.
, p. 3471 - 3475 (2007/10/02)
The reaction of 3,4,6-tri-O-benzyl-D-glucal (2) with 3,3-dimethyldioxirane gives rise to the 2α,3α-oxirane with high stereoselection. Reaction of this compound with various phenols under alkaline conditions affords aryl 2α-hydroxy-β-glycosides (3a-d). Oxi