1252676-64-4Relevant articles and documents
A facile route for stabilizing highly reactive artecl species through the formation of T-Shaped tellurenyl chloride adducts: Quasi-planar zwitterionic [HPy]TeCl2 and [HPm]TeCl2; Py? = 2-pyridyl, Pm? = 2-(4,6-dimethyl)pyrimidyl
Khrustalev, Victor N.,Matsulevich, Zhanna V.,Lukiyanova, Julia M.,Aysin, Rinat R.,Peregudov, Alexander S.,Leites, Larissa A.,Borisov, Alexander V.
, p. 3582 - 3586 (2014)
Two new stable T-shaped tellurenyl chloride adducts, viz., [HPy]TeCl2 (1) and [HPm]TeCl2 (2) [Py? = 2-pyridyl, Pm? = 2-(4,6-dimethyl)pyrimidyl], act as close chemical analogs of highly unstable monomeric PyTeCl and PmTeCl. The quasi-
Cycloaddition of 2-pyridinetellurenyl chloride to alkenes
Borisov,Matsulevich,Osmanov,Borisova,Naumov,Mammadova,Maharramov,Khrustalev,Kachala
, (2012)
The action of 2-pyridinetellurenyl chloride on alkenes results in the polar cycloaddition of the tellurium-centered electrophile at the multiple bond with the formation of 2,3-dihydro[1,3]tellurazolo[3,2-a]pyridinium derivatives.
A facile route for stabilizing highly reactive ArTeCl species through the formation of T-shaped tellurenyl chloride adducts: Quasi-planar zwitterionic [HPy*]TeCl2 and [HPm*]TeCl2; Py* = 2-pyridyl, Pm* = 2-(4,6-dimethyl)pyrimidyl
Khrustalev, Victor N.,Matsulevich, Zhanna V.,Lukiyanova, Julia M.,Aysin, Rinat R.,Peregudov, Alexander S.,Leites, Larissa A.,Borisov, Alexander V.
, p. 3582 - 3586 (2014/08/18)
Two new stable T-shaped tellurenyl chloride adducts, viz., [HPy*]TeCl2 (1) and [HPm*]TeCl2 (2) [Py* = 2-pyridyl, Pm* = 2-(4,6-dimethyl)pyrimidyl], act as close chemical analogs of highly unstable monomeric Py*TeCl and Pm*TeCl. The quasi-planar zwitterionic structures of 1 and 2 have been studied by experimental (X-ray diffraction, multinuclear NMR, IR and Raman spectroscopy) and theoretical (DFT and QTAIM) methods. Thus, a novel facile route to stabilize highly reactive Ar*TeCl species (Ar* = N-functionalized aryl) by the addition of a hydrochloric acid molecule has been demonstrated.