125315-85-7Relevant academic research and scientific papers
Iron-Catalyzed Carboiodination of Alkynes
Deng, Weili,Li, Yajun,Li, You-Gui,Bao, Hongli
, p. 2974 - 2980 (2018)
An iron-catalyzed carboiodination of alkynes with alkyl iodides at room temperature was developed. This method could provide synthetically useful vinyl iodides with general alkyl chains, fluoroalkyl group, ester, and cyano group. Conjugated alkynes or unconjugated alkynes were both suitable for this transformation. A radical pathway was proposed for the mechanism and acetyl tert -butyl peroxide was selected as the radical initiator. Alkenes could also be applied to this chemistry and produce more complex alkyl iodides.
TRIETHYLBORANE-INDUCED RADICAL ADDITION OF ALKYL IODIDES TO ACETYLENES
Ichinose, Yoshifumi,Matsunaga, Shin-ichiro,Fugami,Keigo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3155 - 3158 (2007/10/02)
Treatment of terminal acetylenes (R1CCH) with secondary or tertiary alkyl iodides (R2I) in the presence of triethylborane provides the corresponding alkenyl iodides (R1C(I)=CHR2) in good yields.
