125318-16-3

Upstream product

• 4541-14-4 4-benzyloxy-butan-1-ol 
• 100-39-0 benzyl bromide 
• 5470-84-8 4-benzyloxybutanal 
• 75-64-9 tert-butylamine 

Downstream Products

• 125318-12-9 (-)-benzyloxy-1 hydroxymethyl-3 isopropenyl-6 decadiene-3,9 (3E,6R) 
• 125318-11-8 (-)-benzyloxy-1 isopropenyl-6 decadiene-3,9 carbaldehyde-3 (3E,6R) 
• 1118759-55-9 C₂₄H₂₉NO 
• 1118759-57-1 C₂₅H₃₁NO₂ 
• 5470-84-8 4-benzyloxybutanal 
• 125318-10-7 4-benzyloxy-2-triethylsilylbutanal N-tert-butylimine 

Relevant academic research and scientific papers

Highly stereoselective synthesis of 2,5-disubstituted (E, E)-penta-2,4-dienals

A condensation of α,β-unsaturated aldehydes with O-protected 4-hydroxybutanal N-(tert-butyl)-imine has been exemplified for the first time using (E)-cinnamic and (E)-4-methoxycinnamic aldehydes. (E,E)-2,5-Disubstituted penta-2,4-dienals, which are key intermediates in the synthesis of strobilurins A and X, were prepared in good yields and close to 100% stereoselectivity.

SYNTHESE STEREOSELECTIVE D'UNE COMPOSANTE DE LA PHEROMONE SEXUELLE DE "L'ECAILLE ROUGE DE CALIFORNIE" : L'ACETATE D'ISOPROPENYL-6 METHYL-3 DECADIENE-3,9 YLE (3Z,6R)

The stereospecific elaboration of the trisubstituted double bond of acetate 1, is realized by condensation of an α-silylaldimine with aldehide 5 prepared by regioselective ozonolysis of (+)-limonene.