1253587-48-2Relevant academic research and scientific papers
Protonation/Reduction of Carbonyl-Rich Diiron Complexes and the Direct Observation of Triprotonated Species: Insights into the Electrocatalytic Mechanism of Hydrogen Formation
Liu, Yu-Chiao,Chu, Kai-Ti,Huang, Yi-Lan,Hsu, Cheng-Huey,Lee, Gene-Hsiang,Tseng, Mei-Chun,Chiang, Ming-Hsi
, p. 2559 - 2576 (2016/04/26)
Both the reduced and the protonated states of diiron dithiolate complexes, which are key intermediate species for the electrocatalytic production of hydrogen, have been spectroscopically and theoretically investigated in this study. Five important states
An oxidized active site model for the FeFe hydrogenase: Reduction with hydrogen gas
Matthews, Steven L.,Heinekey, D. Michael
, p. 7925 - 7927 (2011/10/18)
Models for the oxidized form of the FeFe hydrogenase active site have been prepared. These cationic complexes contain two iron atoms, carbonyl ligands, a propanedithiolate bridge, and one other bridging group. Reduction of these complexes with hydrogen ga
A carbonyl-rich bridging hydride complex relevant to the Fe-Fe hydrogenase active site
Matthews, Steven L.,Heinekey, D. Michael
, p. 9746 - 9748 (2011/01/04)
Protonation of Fe2(μ-S2C3H 6)(CO)6 with an acid derived from [SiEt 3][B(C6F5)4] and HCl affords a hydride-bridged dimer.
