1253596-50-7Relevant articles and documents
Nickel-catalyzed C–P cross-coupling of (het)aryl tosylates with secondary phosphine oxides
He, Xiao-Yun
, p. 747 - 752 (2021/02/26)
A novel and convenient approach to the synthesis of various tertiary phosphine oxides via nickel-catalyzed cross-coupling of (het)aromatic tosylates with secondary phosphine oxides is developed. The reaction employs cheap nickel as the catalyst, 1-(2-(di-tert-butylphosphanyl)phenyl)-4-methoxypiperidine (L3) as the ligand, and pyridine as the base. This reaction produces the corresponding (het)aromatic phosphorus compounds in good to high yields. Moreover, four new tertiary phosphine oxides are reported in this process.
Nickel-catalyzed C-P cross-coupling of diphenylphosphine oxide with aryl chlorides
Zhang, Hong-Yu,Sun, Meng,Ma, Yan-Na,Tian, Qiu-Ping,Yang, Shang-Dong
, p. 9627 - 9633 (2013/01/16)
A novel protocol for the preparation of various diarylphosphine oxide compounds via a Ni-catalyzed cross-coupling of aryl chlorides with R 2P(O)H has been developed. Notably, this process exhibits the following very attractive features: (i) the process is simpler and operates under mild reaction conditions; (ii) the process is generally cheaper in part because the more accessible aryl chloride is used to form the C-P bond; (iii) the process avoids the need for simultaneous preparation and use of Ar 2P(O)M. The Royal Society of Chemistry 2012.
Phosphorescent cuprous complexes with N,O ligands - Synthesis, photoluminescence, and electroluminescence
Sun, Wei,Zhang, Qisheng,Qin, Li,Cheng, Yanxiang,Xie, Zhiyuan,Lu, Canzhong,Wang, Lixiang
experimental part, p. 4009 - 4017 (2011/01/10)
Six heteroleptic cuprous complexes, [L1Cu(PPh3) 2](BF4) (1a), [L1Cu(DPEphos)](BF4) (1b), [L2Cu(PPh3)2](BF4) (2a), [L2Cu-(DPEphos)](BF