125364-64-9

Upstream product

• 402-32-4 chlorodimethylsilane 
• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 125364-54-7 1-[(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-3-trifluoromethyl-benzene 
• 125364-55-8 Fluoro-dimethyl-(3-trifluoromethyl-phenyl)-silane 
• 15951-41-4 bis(trimethylsilyl)dichloromethane 
• 125364-60-5 1-[(Dimethylsilanyl-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-3-trifluoromethyl-benzene 
• 1066-35-9 dimethylmonochlorosilane 

Downstream Products

• 125364-73-0 {[Dimethyl-(3-trifluoromethyl-phenyl)-silanyl]-bis-trimethylsilanyl-methyl}-dimethyl-silanol 
• 141868-84-0 1-{[(Methoxy-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-3-trifluoromethyl-benzene 
• 141868-89-5 C₁₉H₃₄F₃NSSi₄ 
• 125364-69-4 1-({[Dimethyl-(2,2,2-trifluoro-ethoxy)-silanyl]-bis-trimethylsilanyl-methyl}-dimethyl-silanyl)-3-trifluoromethyl-benzene 

Relevant academic research and scientific papers

Preparation of the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds

The preparations of: (a) the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) (Y=H, p-OMe, p-Me, p-Cl, m-CF3), via the corresponding hydrides; (b) the compounds (Me3Si)2C(SiMe2Ph)(SiMe2X) with X=F, O2CCF3, OMe, N3, NCS and Cl: and (c) the iodide (p-MeC6H4)3CSiMe2I are described. Key words: Silicon; Iodide; Fluoride; Hydride; Trimethylsilyl

Anchimeric Assistance by γ-Aryl Groups in Solvolysis of Organosilicon Iodides. Some Remarkably Large Remote Substituent Effects

The very large spread of rates in reactions of the iodides (Me3Si)2C(SiMe2C6H4X)(SiMe2I) (X = p-OMe, p-Me, H, p-Cl, or m-CF3) with (CF3)2CHOH and CF3CH2OH (the compound with X = p-OMe is 1.9E05 and 6.5E04 times, respectively, as reactive as that with X = m-CF3) is attributed to nucleophilic assistance by the aryl group to the leaving of the I- ion.