125408-50-6

Basic information

• Product Name: (6-Allyl-3-ethoxy-3-methyl-cyclohex-1-enyloxy)-trimethyl-silane
• CAS NO: 125408-50-6
• Molecular Weight: 268.472
• Mol File: 125408-50-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (6-Allyl-3-ethoxy-3-methyl-cyclohex-1-enyloxy)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (6-Allyl-3-ethoxy-3-methyl-cyclohex-1-enyloxy)-trimethyl-silane(125408-50-6)
• EPA Substance Registry System: (6-Allyl-3-ethoxy-3-methyl-cyclohex-1-enyloxy)-trimethyl-silane(125408-50-6)

Safety Data

• Hazardous Substances Data: 125408-50-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 89984-56-5 methyl manganese chloride 
• 58775-54-5 (+/-)-3-ethoxy-6-(prop-2-enyl)-cyclohex-2-en-1-one 

Downstream Products

• 84695-64-7 6-allyl-3-methyl-cyclohex-2-enone 

Relevant articles and documents

ORGANOMANGANESE (II) REAGENTS XVI: COPPER-CATALYZED 1,4-ADDITION OF ORGANOMANGANESE CHLORIDES TO CONJUGATED ENONES

Copper-catalyzed conjugate addition of organomanganese chlorides to conjugated enones in THF, at 0 deg C, leads to the 1,4-addition products in high yields.The scope of the reaction is very large and the results are generally better than those obtained from organomagnesium compounds in the presence of a copper salts as well as from organocopper or cuprate reagents.Furthermore organomanganese chlorides are indisputably cheaper and more stable than the latter.