125556-65-2Relevant academic research and scientific papers
Generation of F-Alkyl-substituted Vinyl Thionium Ion Intermediates and Their Reation with Silyl Enol Ethers. A New Route of δ-F-Alkyl-α,β:γ,δ-unsaturated Carbonyl Compounds
Ishihara, Takashi,Shinozaki, Takao,Kuroboshi, Manabu
, p. 1369 - 1372 (2007/10/02)
Treatment of 3-F-alkyl-3-fluoro-2-propenyl phenyl or ethyl sulfoxide with trimethylsilyl triflate and a hindered amine produces the corresponding vinyl thionium ion species, which readily reacts with silyl enol ethers to give δ-F-alkylated γ,δ-unsaturated
